Journal
TRAC-TRENDS IN ANALYTICAL CHEMISTRY
Volume 53, Issue -, Pages 98-105Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.trac.2013.09.014
Keywords
Calibration-free measurement; Chronopotentiometry; Dynamic electrochemistry; Ion-selective electrode; Ion speciation; Ion-transfer voltammetry; Liquid-liquid electrochemistry; Polymeric membrane electrode; Stripping ion-transfer voltammetry; Thin-layer coulometry
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This review aims to highlight a recent important direction to place ion-selective electrodes based on polymeric sensing materials under dynamic electrochemistry control. This allows one to design sensors with a range of improved characteristics. This review also showcases developments to achieve calibration-free ion-sensing strategies by using thin layer coulometry at ion-selective membranes. Finally, strategies to fabricate electrochemically-addressable ion-selective thin membrane layers are discussed, especially in view of realizing stripping ion-transfer voltammetric sensors. (C) 2013 Elsevier Ltd. All rights reserved.
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