Journal
TRAC-TRENDS IN ANALYTICAL CHEMISTRY
Volume 55, Issue -, Pages 55-67Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.trac.2013.12.004
Keywords
Ambient mass spectrometry; Atmospheric pressure ionization mass spectrometry; Coupling; Electron-impact mass spectrometry; Inductively-coupled plasma mass spectrometry; Interface; Laser-desorption/ionization mass spectrometry; Mass spectrometry; Sample pretreatment; Solid-phase microextraction
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Funding
- National Natural Science Foundation of China (NSFC) [21277177, 21307167]
- Scientific and Technological Project of Guangdong Province [2011B060100005]
- South China Sea Branch of State Oceanic Administration
- Administration of Ocean and Fisheries of Guangdong Province
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Solid-phase microextraction (SPME) has experienced significant development since its introduction as a sample-pretreatment technique in the early 1990s. SPME is suitable for interfacing with chromatography and mass spectrometry (MS), but progress in coupling with chromatography has exceeded that with MS. In the past two decades, efforts have been made to couple SPME and MS with different applications in various research fields. Based on these previous studies, this review article summarizes historical developments, principles and operation, practical applications, and recent trends in SPME coupled with five types of MS: (1) electron-impact MS, (2) inductively-coupled plasma MS, (3) laser-desorption/ionization MS, (4) atmospheric-pressure ionization MS and (5) ambient MS CAMS). We particularly emphasize efforts on SPME coupled with AMS. (C) 2014 Elsevier Ltd. All rights reserved.
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