4.7 Article

Analysis of inorganic chloramines in water

Journal

TRAC-TRENDS IN ANALYTICAL CHEMISTRY
Volume 33, Issue -, Pages 55-67

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.trac.2011.10.006

Keywords

Amperometry; Chemical reagent; Colorimetry; Derivatization; Gas chromatography; High-performance liquid chromatography; Inorganic chloramine; Limit of quantitation; Mass spectrometry; Titrimetry

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This article describes the state of the art of the methods used for analysis of inorganic chloramines in water. After we introduce the physicochemical properties, the use and the toxicity of inorganic chloramines, we describe methods with little or no specificity (e.g., colorimetry, titrimetry and amperometry) and the chemical reagents used in these methods. We also introduce methods involving more specific techniques (e.g., high-performance liquid chromatography and mass spectrometry). We compare the performances of all these methods in terms of specificity, selectivity, limits of quantitation, ease of operation and possibility of automation. (C) 2012 Elsevier Ltd. All rights reserved.

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