4.4 Article

Pt-supported Spherical Mesoporous Silica as a Nanosized Catalyst for Efficient Liquid-Phase Hydrogenation

Journal

TOPICS IN CATALYSIS
Volume 57, Issue 10-13, Pages 1026-1031

Publisher

SPRINGER/PLENUM PUBLISHERS
DOI: 10.1007/s11244-014-0266-8

Keywords

Mesoporous silica; Spherical nanocatalyst; Hydrogenation; Platinum

Funding

  1. Ministry of Education, Culture, Sports, Science and Technology of Japan [237607430]
  2. MEXT
  3. Grants-in-Aid for Scientific Research [26620194, 26630409, 23360356, 26220911] Funding Source: KAKEN

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Mesoporous silica nanospheres with an average diameter of approximately 240 and 600 nm have been used as catalyst supports of active Pt nanoparticles, which were found to be highly efficient for liquid-phase hydrogenation under atmospheric H-2 compared to the micron-sized conventional mesoporous silica because of the suppression of mass-transport limitation toward active sites.

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