Journal
TOPICS IN CATALYSIS
Volume 57, Issue 10-13, Pages 1103-1111Publisher
SPRINGER/PLENUM PUBLISHERS
DOI: 10.1007/s11244-014-0275-7
Keywords
Perovskites; Non-noble metals; Selox; Cobalt; Cerium
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Funding
- CNPq
- CAPES
- FINEP
- MCT
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Perovskite-type oxides La1-xMxCoO3 (M = Ce, Sr) were prepared by citrate method, characterized and evaluated in the selective CO oxidation (SELOX-CO). The insertion of low Cerium or Strontium content generated solids with a single phase related LaCoO3 perovskite. For higher contents we observed segregation of CeO2 and SrCO3. The iso-structural substitution favors the formation of vacancies. The SELOX-CO showed 100 % CO conversion at 200 degrees C. Higher temperatures favored hydrogen oxidation and methanation.
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