Journal
TOPICS IN CATALYSIS
Volume 56, Issue 13-14, Pages 1154-1170Publisher
SPRINGER/PLENUM PUBLISHERS
DOI: 10.1007/s11244-013-0082-6
Keywords
Pd nanoparticles; Supported catalyst; Cross-coupling; Carbon-carbon bond formation
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Funding
- Spanish MINECO/FEDER [MAT2010-15374, CTQ2010-16390]
- Xunta de Galicia/FEDER [10PXIB314218PR]
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We intent to present an overview of the available catalysts for the carbon-carbon cross-coupling reactions based on supported palladium (Pd) nanoparticles (NPs). We begin this perspective with a brief introduction about the cross-coupling reactions and the mechanistic implications of using Pd NPs as catalyst, i.e. heterogeneous versus homogeneous catalysis, then we summarize some of the most versatile Pd supported catalysts as a function of its nature. The supported catalysts have been classified in inorganic, organic and hybrid supports. Finally we outline the perspectives for the development of new Pd supported catalysts.
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