Journal
TOPICS IN CATALYSIS
Volume 55, Issue 11-13, Pages 889-896Publisher
SPRINGER/PLENUM PUBLISHERS
DOI: 10.1007/s11244-012-9857-4
Keywords
Lignin gasification; Supercritical water; Supported metal catalysts; X-ray absorption near edge structure; Extended X-ray absorption fine structure
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Funding
- Special Coordination Funds for Promoting Science and Technology of Ministry of Education, Culture, Sports, Science and Technology (MEXT), Japan
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Charcoal supported metal salt catalysts showed activities for the lignin gasification at 673 K, especially the catalysts without chloride anion showed the complete gasification. The order of activity for the gasification among the metal species was following: ruthenium > rhodium > platinum > palladium similar to nickel. X-ray absorption fine structure analysis revealed that small metal particles were formed on the charcoal support after the gasification for the supported ruthenium, rhodium, and platinum salt catalysts without chloride anion; on the other hand, larger metal particles were formed in the presence of chloride anion. Lower activities and deactivation for supported metal salt catalysts having the chloride anion were caused by poisoning by chloride anions and the smaller number of metal sites.
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