Journal
TOPICS IN CATALYSIS
Volume 54, Issue 13-15, Pages 998-1008Publisher
SPRINGER/PLENUM PUBLISHERS
DOI: 10.1007/s11244-011-9721-y
Keywords
1-Hexene oligomerization; Catalysis by ion-exchange resins
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Funding
- Repsol YPF
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Oligomerization of pure 1-hexene catalyzed by macroporous ion-exchange resins was performed in batch experiments at 350-390 K and 2 MPa. At 373 K, after 6 h, 1-hexene conversion was practically complete and the selectivity to dimers was 56%, that to trimers 0.8 and 43.2% to double-bond isomerization. By assuming an homogeneous kinetic model for olefin dimerization of second order reaction, a value of 64-68 kJ mol(-1) for apparent activation energy was obtained.
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