4.4 Article

Catalytic Generation of Hydrogen from Formic acid and its Derivatives: Useful Hydrogen Storage Materials

Journal

TOPICS IN CATALYSIS
Volume 53, Issue 13-14, Pages 902-914

Publisher

SPRINGER/PLENUM PUBLISHERS
DOI: 10.1007/s11244-010-9522-8

Keywords

Formic acid; Hydrogen; Hydrogen storage; Energy; Catalysis; Ruthenium; Carbon dioxide

Funding

  1. State of Mecklenburg-Vorpommern
  2. BMBF
  3. DFG [1213]

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In this account the concept of using formic acid as a hydrogen storage material is presented. Catalytic reduction of carbon dioxide and heterogeneously catalyzed decomposition of formic acid to hydrogen and carbon dioxide are briefly discussed. In the main part the historic development and recent examples of homogeneously catalyzed hydrogen generation from formic acid are covered in detail.

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