Journal
TOPICS IN CATALYSIS
Volume 53, Issue 15-18, Pages 1110-1113Publisher
SPRINGER/PLENUM PUBLISHERS
DOI: 10.1007/s11244-010-9542-4
Keywords
TEMPO; Oxidation; Heterogeneous; Recyclable; Catalyst
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Organically modified silica-based SiliaCat TEMPO is an oxidizing catalyst that can efficiently replace other homogeneous stable nitroxyl radicals. Its high activity, reusability, leach-proof properties, selectivity towards the oxidation of alcohols into aldehydes/ketones and its capacity to carry out the oxidation in either organic solvents or water, with or without KBr as co-catalyst, have shown that this material is green chemistry driven.
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