Journal
TOPICS IN CATALYSIS
Volume 53, Issue 3-4, Pages 141-153Publisher
SPRINGER/PLENUM PUBLISHERS
DOI: 10.1007/s11244-009-9419-6
Keywords
Mesoporous molecular sieves; MCM-41; SBA-15; Mesoporous alumina; Metathesis; C-C coupling; Base catalyzed reactions; Acylation reactions; Ionic liquids; Immobilization
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Funding
- Spanish Ministerio de Educacion y Ciencia [MAT2007-66439-C02-01]
- Academy of Sciences of the Czech Republic [KAN100400701]
- Grant Agency of the Academy of Sciences of the Czech Republic [IAA400400805]
- Grant Agency of the Czech Republic [104/09/0561]
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This overview covers the recent achievements in the application of mesoporous molecular sieves as catalysts and catalyst supports. Main structural and textural features are outlined in relation to the novel synthesis approaches of mesoporous molecular sieves and understanding of their properties. For application of mesoporous molecular sieves as catalysts different ways of introduction of active sites on their surfaces are provided. The main part describes selected catalytic reactions catalyzed by mesoporous molecular sieves focused on very recent papers. The examples include metathesis, acylation reactions, C-C coupling reactions of Heck and Suzuki types, base-catalyzed reactions (Knoevenagel and Michael additions, Claisen-Schmidt condensation, Tischenko reaction) and last but not least immobilization of organometallic complexes for different catalytic applications including chiral catalysts.
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