Journal
TOPICS IN CATALYSIS
Volume 52, Issue 6-7, Pages 823-827Publisher
SPRINGER/PLENUM PUBLISHERS
DOI: 10.1007/s11244-009-9233-1
Keywords
Perovskite-type oxide; SmFeO3; SmCoO3; Catalytic activity; CO oxidation; Synergistic effect
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The perovskite-type SmFe (x) Co1-x O-3 oxides were prepared by the thermal decomposition of heteronuclear cyano complexes, Sm[Fe (x) Co1-x (CN)(6)] a (TM) nH(2)O. XRD studies demonstrated that SmFe (x) Co1-x O-3 catalyst prepared by the thermal decomposition of heteronuclear cyano complex at 1,273 K showed orthorhombic structure in whole range of x. The catalytic activity for CO oxidation was dependent on x in SmFe (x) Co1-x O-3; the maximum activity was obtained for SmFe0.5Co0.5O3.
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