4.4 Article Proceedings Paper

NH3-Slip Catalysts: Experiments Versus Mechanistic Modelling

Journal

TOPICS IN CATALYSIS
Volume 52, Issue 13-20, Pages 1847-1851

Publisher

SPRINGER/PLENUM PUBLISHERS
DOI: 10.1007/s11244-009-9351-9

Keywords

Pt; Kinetic modelling; Ammonia oxidation; Slip catalyst

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The oxidation of ammonia on a Pt/Al2O3 coated monolith has been studied under automotive NH3-slip catalyst conditions. Ammonia conversion as well as the selectivities towards the products N-2, N2O and NO are well described by a mechanistic model that is based on reaction mechanisms originally developed for NH3 oxidation in nitric acid production plants.

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