Journal
TOPICS IN CATALYSIS
Volume 47, Issue 1-2, Pages 32-41Publisher
SPRINGER/PLENUM PUBLISHERS
DOI: 10.1007/s11244-007-9032-5
Keywords
metal nanoparticles; silver nanoparticles; ligand-coated nanoparticles; order-disorder transition; nanoparticle solubility; nanoparticle assemblies
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The solubility of alkylthiol-coated silver nanoparticles and the energetics of the ligand disordering have been investigated. Calorimetry measurements have provided correlations between the nature of the ligands and the enthalpy of the ligand disordering, which have guided the improvement of nanoparticle solubility and dispersion in organic media.
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