Journal
THIN SOLID FILMS
Volume 554, Issue -, Pages 102-105Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.tsf.2013.08.023
Keywords
Poly(3,4-ethylenedioxythiophene); 3D micropattern; Multi-photon sensitized polymerization
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Funding
- Shinkawa, Ltd.
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A dimeric compound of 3,4-ethylenedioxythiophene was polymerized to form poly(3,4-ethylenedioxythiophene) by multi-photon sensitized polymerization using a femtosecond laser. In contrast, photopolymerization could not be achieved using 3,4-ethylenedioxythiophene as the starting material, because it has a more positive oxidation peak potential compared to the redox potential of the tris(2,2'-bipyridyl) ruthenium complex used as the photosensitizer. Furthermore, three-dimensional micropatterns of poly(3,4-ethylenedioxythiophene) could be produced in a transparent polymer sheet by scanning the laser focal point. (C) 2013 Elsevier B.V. All rights reserved.
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