Journal
THIN SOLID FILMS
Volume 516, Issue 9, Pages 2396-2400Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.tsf.2007.04.055
Keywords
ultraviolet photoemission spectroscopy; X-ray photoemission spectroscopy; electrospray deposition; highly oriented pyrolytic graphite; ribonucleic acid; nucleobases; ionization energy
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Previous results showed significant ionization energy differences between thin films of the four ribonucleic acid (RNA) polynucleotides. The experiments reported here aim at the investigation of the origin of these differences. Since the ribose phosphate backbone is common to all RNA nucleotides, the nucleobases are the most likely candidate defining the ionization energy of RNA. Consequently, experiments were performed to investigate the electronic structure and ionization energies of thin films of two nueleobases (adenine and uracil, representative for purines and pyrimidines), and ribose phosphate. These experiments were performed using x-ray and ultraviolet photoemission spectroscopy (XPS, UPS) in conjunction with an electrospray based in vacuum multi-step deposition technique. The presented results clearly demonstrate a significant ionization energy difference between the two nucleobases, qualitatively matching the previous results on the homopolymers of adenosine and uridine (poly rA, poly rU). As expected, the ionization energy of the prepared ribose phosphate thin films was much larger than those of the nucleobases. (C) 2007 Elsevier B.V. All rights reserved.
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