Journal
THERMOCHIMICA ACTA
Volume 547, Issue -, Pages 120-125Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.tca.2012.07.020
Keywords
Polymers; Thermal degradation; Thermogravimetry; Simultaneous thermal analysis
Funding
- National Basic Research Program of China (973 Program) [2012CB719702]
- National Natural Science Foundation of China [50976110, 51076065]
- Key Technologies R&D Program of China [2011BAK07B01-02]
- Fundamental Research Funds for the Central Universities [WK2320000014]
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The thermal degradation of three typical organic insulation materials, rigid polyurethane (PU) foam, extruded polystyrene (XPS) and expanded polystyrene (EPS) were investigated using thermogravimetry (TG) and simultaneous thermal analysis (STA) coupled with mass spectrometry and Fourier transform infrared spectroscopy (TG-DSC-MS-FTIR). The Kissinger-Akahira-Sunose method was utilized for calculating the activation energy values of the materials. Volatile products obtained from the degradation were identified by MS and FTIR. The results of TG-DTG-DSC curves under 10 degrees C/min heating rate in a nitrogen environment revealed the differences in characteristics of the three materials during the thermal degradation. Only one obvious mass loss stage of EPS was observed, and XPS shows two degradation stages and the second one is the main stage. While PU is more complex, and the degradation process involves three steps and the whole mass loss is continuous. The largest heat absorption is in the main mass loss stage. (C) 2012 Elsevier B.V. All rights reserved.
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