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Effect of structural and thermodynamic factors on the sorption of hydrogen by metal-organic framework compounds

Journal

THEORETICAL AND EXPERIMENTAL CHEMISTRY
Volume 45, Issue 2, Pages 75-97

Publisher

SPRINGER
DOI: 10.1007/s11237-009-9068-7

Keywords

metal-organic frameworks; porous coordination polymers; hydrogen sorption

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The characteristics of the sorption of hydrogen by metal-organic framework compounds (MOF) were examined, and the structural and thermodynamic factors that favor the sorption of H-2 by such substances were determined. The effect of the structure of the MOF and the size and geometry of the pores on the sorption characteristics was analyzed.

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