Journal
TETRAHEDRON-ASYMMETRY
Volume 25, Issue 5, Pages 457-461Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetasy.2014.01.008
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Funding
- DST New Delhi [IFA12-CH-30]
- CSIR, New Delhi
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A new prolinamide derivative phthalimido-prolinamide 1 was developed for organocatalytic enantioselective direct aldol reactions of various aldehydes with ketones. The catalytic protocol is effective with 15 mol % of catalyst under solvent free and additive free reaction conditions. By employing a catalytic amount of water, the efficiency of the reaction increased further and the desired products beta-hydroxy carbonyl compounds were obtained in high yields and stereoselectivities. (C) 2014 Elsevier Ltd. All rights reserved.
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