Journal
TETRAHEDRON-ASYMMETRY
Volume 25, Issue 12, Pages 949-955Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetasy.2014.05.005
Keywords
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Funding
- Natural Science Foundation of China [21102116]
- Innovative Research Team in College of Sichuan Province [14TD0016]
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Chiral primary amine catalyzed direct asymmetric aldol reactions of ketones with trifluoroacetophenone, afforded trifluoromethylated beta-hydroxycarbonyl aldol products bearing a quaternary carbon stereogenic center in high yields (up to 93% yield) and with high to excellent enantioselectivities of up to 99% ee. (C) 2014 Elsevier Ltd. All rights reserved.
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