Journal
TETRAHEDRON-ASYMMETRY
Volume 24, Issue 8, Pages 499-504Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetasy.2013.03.008
Keywords
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Funding
- Ministry of Education, Culture, Sports, Science and Technology, Japan [WAKATE B-22750082]
- COE Start-up Program in Chiba University
- Grants-in-Aid for Scientific Research [22750082, 25288017, 24655025] Funding Source: KAKEN
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The palladium-catalyzed asymmetric allylic alkylation of indoles with 1,3-diphenyl-2-propenyl acetate using P/N-type ligands such as N-aryl indole, C-N bond axially chiral aminophosphine (aS)-I4, gave the desired products 1 in good yields and with moderate to high enantioselectivities (up to 90% ee). (C) 2013 Elsevier Ltd. All rights reserved.
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