Journal
TETRAHEDRON-ASYMMETRY
Volume 23, Issue 6-7, Pages 468-473Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetasy.2012.03.023
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A series of polyvinylidene chloride (PVDC)-supported ionic liquids were derived from 4-dimethylamino-pyridine and used together with L-proline in water as efficient asymmetric organocatalysts for direct asymmetric aldol reactions between cyclohexanone and a variety of aromatic aldehydes at room temperature. These PVDC-supported ionic liquids/L-proline catalyst systems have been used as asymmetric organocatalysts to afford the corresponding aldol products with a moderate to high isolated yield of up to 99%, with diastereoselectivity of up to 6:94, and excellent enantioselectivity of up to 98%. Furthermore, they could be easily recycled and showed only a slight reduction in selectivity after seven recycles. (C) 2012 Elsevier Ltd. All rights reserved.
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