Journal
TETRAHEDRON-ASYMMETRY
Volume 23, Issue 13, Pages 1019-1022Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetasy.2012.06.004
Keywords
-
Funding
- Korea Science and Engineering Foundation (KOSEF)
- Korean Government (MEST) [R01-2008-000-20332-0]
Ask authors/readers for more resources
An optimal hydrophobic ionic liquid was discovered as a solvent for highly enantioselective glyoxylateene reactions catalyzed by a chiral bis(oxazoline)-copper complex. The reactivity and stereoselectivity were highly dependent upon the property of the ionic liquids; reactions between olefins and ethyl glyoxylate in [Bmim]SbF6 at ambient temperature provided remarkably enhanced reactivity and stereoselectivity, which greatly exceed those of the corresponding reactions in dichloromethane. Furthermore, the metal-ligand complex was readily recycled up to eight times while exhibiting no significant decrease in reaction efficiency. (C) 2012 Elsevier Ltd. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available