4.0 Article

Vanadium-catalyzed enantioselective oxidation of allyl sulfides

Journal

TETRAHEDRON-ASYMMETRY
Volume 22, Issue 7, Pages 717-721

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetasy.2011.04.023

Keywords

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Funding

  1. National Science Foundation of China [20672088, 20705031]
  2. Ministry of Human Resources and Social Security of China
  3. Science and Technology Bureau of Sichuan [2011HH0016]
  4. Chengdu Science and Technology Bureau
  5. Chengdu University of Technology

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The enantioselective oxidation of allyl sulfides with a vanadyl complex of 3,5-diiodosalicylidene tert-leucinol as a catalyst and aqueous hydrogen peroxide as an oxidant afforded chiral allylsulfoxides with high enantioselectivities of up to 97.3% ee and moderate yields. (C) 2011 Elsevier Ltd. All rights reserved.

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