Journal
TETRAHEDRON-ASYMMETRY
Volume 22, Issue 10, Pages 1074-1080Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetasy.2011.06.017
Keywords
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Funding
- National Natural Science Foundation of China [20802025]
- Jilin Provincial Science & Technology Sustentation Program [20090585, 20100538]
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Simple N-proline-based dipeptides with two N-H groups in combination with 2,4-dinitrophenol (DNP) catalyze the direct asymmetric aldol reactions of aldehydes with a broad range of ketones to furnish the corresponding aldol products in high yields (up to 99%) and with high enantioselectivities (up to 97%) and diastereoselectivities (up to > 99:1, anti/syn) at room temperature and in brine. (C) 2011 Elsevier Ltd. All rights reserved.
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