Journal
TETRAHEDRON-ASYMMETRY
Volume 22, Issue 23, Pages 2029-2038Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetasy.2011.12.004
Keywords
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Funding
- Shanghai Municipal Committee of Science and Technology [08dj1400100-2]
- National Basic Research Program of China (973) [2010CB833302]
- Fundamental Research Funds for the Central Universities
- National Natural Science Foundation of China [21072206, 20472096, 20902019, 20872162, 20672127, 20821002, 20732008, 20702059]
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A class of axially chiral NHC-Au(I) complexes has been applied to the asymmetric Friedel-Crafts/cyclization reaction of nitrogen-tethered 1,6-enynes 14 with indole derivatives 15, affording the corresponding Friedel-Crafts and intramolecular cyclization products 16 in good yields and with moderate ee values under mild conditions. (C) 2011 Elsevier Ltd. All rights reserved.
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