Journal
TETRAHEDRON-ASYMMETRY
Volume 21, Issue 9-10, Pages 1075-1084Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetasy.2010.05.035
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Funding
- CNRS
- UPMC
- COST Action [D40]
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An escapade in the world of sulfenate anions is described and shows that these nucleophiles, despite being described as unstable species, are mild and efficient sulfinylating agents, allowing access to a variety of allyl and aryl sulfoxides under smooth and operationally very simple conditions. Their use in asymmetric catalysis is also possible allowing the preparation of enantio-enriched sulfoxides. Moreover, such anions have been involved in the development of two new pseudo-domino processes. (C) 2010 Elsevier Ltd. All rights reserved.
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