Journal
TETRAHEDRON-ASYMMETRY
Volume 21, Issue 8, Pages 943-951Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetasy.2010.05.025
Keywords
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Funding
- Shanghai Municipal Committee of Science and Technology [06XD14005, 08dj1400100-2]
- National Basic Research Program of China (973) [2010CB833302]
- National Natural Science Foundation of China [20902019, 20872162, 20672127, 20821002, 20732008, 20702059]
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Axially chiral phosphine-oxazoline ligand L7, prepared from (S)-binol, was found to be a fairly effective chiral ligand in the silver(I)-catalyzed asymmetric Mannich reaction of fluorinated aldimines with trimethylsiloxyfuran to give the corresponding adducts in up to 99% yield, over 20:1 dr and 81% ee. (C) 2010 Elsevier Ltd. All rights reserved.
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