4.0 Article

Models for the basis of enantioselection in palladium mediated C-H activation reactions

Journal

TETRAHEDRON-ASYMMETRY
Volume 21, Issue 23, Pages 2782-2787

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetasy.2010.10.014

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Funding

  1. EPSRC
  2. Scientific and Technological Research Council of Turkey (TUBITAK)
  3. Engineering and Physical Sciences Research Council [EP/E06356X/1] Funding Source: researchfish
  4. EPSRC [EP/E06356X/1] Funding Source: UKRI

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Models are proposed to account for the basis of enantioselection in cyclopalladation reactions, which result in the formation of planar chiral palladacycles. This analysis is extended to a palladium catalysed enantioselective C-H activation reaction proceeding via the intermediacy of a chiral palladacycle. (C) 2010 Elsevier Ltd. All rights reserved.

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