Journal
TETRAHEDRON-ASYMMETRY
Volume 21, Issue 18, Pages 2281-2288Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetasy.2010.08.004
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Funding
- MICINN [CTQ2008-00950/BQU]
- DURSI [2009GR623]
- Consolider Ingenio [CSD2006-0003]
- ICIQ Foundation
- Programa Torres y Quevedo
- ICREA Funding Source: Custom
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A library of highly modular P-OP ligands have been evaluated in Pd-catalysed allylic substitutions with C- and N-nucleophiles. Catalyst optimisation via a variation of the phosphino and phosphite substituents led to a 'lead' catalyst, which efficiently mediated the allylic substitutions when various combinations of substrates and nucleophiles were tested. Ground-state calculations were carried out and these allowed a clearer understanding of the stereochemical outcome of the reaction. (C) 2010 Elsevier Ltd. All rights reserved.
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