Journal
TETRAHEDRON-ASYMMETRY
Volume 21, Issue 15, Pages 1936-1941Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetasy.2010.06.037
Keywords
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Funding
- National Science and Technology Ministry of China [2007BAI34B05]
- Zhejiang Provincial Natural Science Foundation of China [Y4090052]
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A series of novel carbohydrate-based iminophosphinite ligands have been synthesized for the first time and successfully applied in Pd-catalyzed asymmetric allylic alkylation. The substituent effects on the catalytic reaction were also investigated, and 92% ee was achieved when the p-nitro-substituted ligand 10d was used. Crown Copyright (C) 2010 Published by Elsevier Ltd. All rights reserved.
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