Journal
TETRAHEDRON-ASYMMETRY
Volume 21, Issue 15, Pages 1928-1935Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetasy.2010.06.041
Keywords
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Funding
- Shanghai Municipal Committee of Science and Technology [06XD14005, 08dj1400100-2]
- National Basic Research Program of China [2010CB833302]
- National Natural Science Foundation of China [20902019, 20872162, 20672127, 20821002, 20732008, 20702059]
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Chiral C-2-symmetric N-heterocyclic carbene (NHC) palladium diaquo complexes 5a-c and the chiral C-2-symmetric NHC-palladium complexes 5d and 5e prepared from (R)-BINAM or H-8-(R)-BINAM could be used as the catalysts for the enantioselective arylation of arylaldehydes with arylboronic acids in which NHC-Pd complex 5a was found to be fairly effective in this reaction to give the corresponding adducts in moderate enantioselectivities along with moderate to good yields. (C) 2010 Elsevier Ltd. All rights reserved.
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