Journal
TETRAHEDRON-ASYMMETRY
Volume 21, Issue 18, Pages 2193-2197Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetasy.2010.07.034
Keywords
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Funding
- Korean Government [2009-0075833]
- National Research Foundation of Korea [2009-0075833] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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Advances in the palladium-catalyzed asymmetric hydrosilylation of 1,3-dienes are presented according to substrate types and chiral monophosphine ligands. Chiral monodentate phosphine ligands with a binaphthyl moiety have been proven to be the most efficient ligands for cyclic 1,3-dienes, and planar chiral ferrocenylmonophosphine ligands with two ferrocenyl moieties for linear 1,3-dienes. The ferrocenylmonophosphine ligands have expanded the substrate scope to 1,3-enynes in the asymmetric hydrosilylation. Palladium-catalyzed asymmetric hydrosilylation of 1,3-dienes and 1,3-enynes leads to the stereoselective synthesis of allylsilanes and allenylsilanes, respectively. (C) 2010 Elsevier Ltd. All rights reserved.
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