Journal
TETRAHEDRON-ASYMMETRY
Volume 21, Issue 8, Pages 891-894Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetasy.2010.05.027
Keywords
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Funding
- Ministry of Education, Culture, Sports, Science and Technology, Japan
- Takeda Science Foundation
- Grants-in-Aid for Scientific Research [22790010] Funding Source: KAKEN
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A new class of acid-base chiral organocatalysts 1a and 2 for aza-Morita-Baylis-Hillman (aza-MBH) reaction of conjugated nitroalkenes is described. The acidic phenolic hydroxy groups and basic imidazole unit cooperatively activate nitroalkenes to promote the aza-MBH reaction in good yields with moderate enantioselectivities. (C) 2010 Elsevier Ltd. All rights reserved.
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