Journal
TETRAHEDRON-ASYMMETRY
Volume 21, Issue 9-10, Pages 1216-1220Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetasy.2010.03.003
Keywords
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Funding
- National Natural Science Foundation of China
- Major Basic Research Development Program [2006CB806106]
- Ministry of Education of China [B06005]
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A palladium-catalyzed asymmetric umpolung allylation reaction of imines with allylic alcohols has been developed. In the presence of chiral Spiro phosphoramidite ligand 4, the allylation was accomplished with high yields and good enantioselectivities. The use of highly stable and easily available allylic alcohols instead of allylic metal reagents facilitated the preparation of chiral homoallylic amines. (C) 2010 Elsevier Ltd. All rights reserved.
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