Journal
TETRAHEDRON-ASYMMETRY
Volume 20, Issue 9, Pages 1086-1092Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetasy.2009.03.040
Keywords
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Funding
- The Shanghai Municipal Committee of Science and Technology [06XD14005, 08dj1400100-2]
- National Basic Research Program of China [(973)-2009CB825300]
- National Natural Science Foundation of China [20472096, 20872162, 20672127, 20821002, 20732008]
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Enantioselective allylic substitution of Morita-Baylis-Hillman (MBH) acetates with phthalimide was realized in the presence of a novel L-proline-derived chiral trifunctional phosphine amide ligand to give the corresponding allylic amination adducts in good yields (70-95%) and in modest to good enantioselectivities (34-78% ee's). (c) 2009 Elsevier Ltd. All rights reserved.
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