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Efficient chirality switching in the asymmetric addition of indole to N-tosylarylimines in the presence of axially chiral cyclometalated bidentate N-heterocyclic carbene palladium(II) complexes

TETRAHEDRON-ASYMMETRY (2009)

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Journal

TETRAHEDRON-ASYMMETRY
Volume 20, Issue 1, Pages 119-123

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetasy.2008.11.015

Keywords

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Categories

Chemistry, Inorganic & Nuclear Chemistry, Organic Chemistry, Physical

Funding

  1. Shanghai Municipal Committee of Science and Technology [06XD14005, 08dj1400100-2]
  2. National Basic Research Program of China [(973)-2009CB825300]
  3. National Natural Science Foundation of China [20872162, 20672127, 20732008]

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Efficient dual stereocontrol can be achieved by using axially chiral cyclometalated bidentate N-heterocyclic carbene palladium(II) complexes for the addition of indole to N-tosylarylimines simply by the adjustment of the R group on the benzene rings of the NHC-Pd(II) complexes. (C) 2008 Elsevier Ltd. All rights reserved.

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