Journal
TETRAHEDRON-ASYMMETRY
Volume 20, Issue 24, Pages 2866-2870Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetasy.2009.11.016
Keywords
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Funding
- Swiss National Research Foundation [200020-113332]
- COST action D40 [C07.0097]
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Herein we report the copper-catalyzed asymmetric conjugate addition of Grignard reagents to cyclic and acyclic enones. with SimplePhos as chiral ligands. A variety of Grignard reagents can be added to a range of cyclic and acyclic enones, with moderate to good enantioselectivities (ee's up to 86%). (C) 2009 Elsevier Ltd. All rights reserved.
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