Journal
TETRAHEDRON-ASYMMETRY
Volume 20, Issue 12, Pages 1437-1444Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetasy.2009.05.023
Keywords
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Funding
- NSERC
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Rhodium complexes of (R)-Me-CATPHOS and (R)-(S)-JOSIPHOS form a complementary pair of catalysts for the highly efficient asymmetric hydrogenation of a selection of (E)- and (Z)-beta-aryl-beta-(enamido)phosphonates, respectively, in the majority of cases giving excellent yields and ee's in excess of 99%: the highest to be reported for this Class Of substrate. (C) 2009 Elsevier Ltd. All rights reserved.
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