Journal
TETRAHEDRON-ASYMMETRY
Volume 19, Issue 10, Pages 1189-1192Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetasy.2008.04.019
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The Rh-catalyzed asymmetric hydrogenation of prochiral beta-N-acetylamino-vinylphosphoniites allows the preparation of chiral beta-N-acetylamino-phosphonates with excellent yields (up to 100%) and. high enantioselectivities (up to 92% ee). The reaction is strongly dependent on the chiral bidentate phosphorus ligand and the solvent employed. In several cases an inversion of the induced chirality was noted by using the corresponding E- or Z-isomeric substrates. (C) 2008 Elsevier Ltd. All rights reserved.
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