4.4 Article

Transition-metal-catalyzed ketone-directed ortho-C-H functionalization reactions

Journal

TETRAHEDRON LETTERS
Volume 55, Issue 6, Pages 1121-1126

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2013.12.107

Keywords

Transition-metal-catalyzed; C-H functionalization; Ketones

Funding

  1. National Science Foundation of China [21172006]
  2. National Young Top-notch Talent Support Program
  3. Ph.D. Programs Foundation of the Ministry of Education of China [20120001110013]
  4. Ningxia University

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In the past 20 years, organic chemists have made significant contributions to the development of transition-metal-catalyzed ketone-directed ortho-C-H functionalization. These include Ru, Rh, Pd, and Ir-catalyzed ketone-directed C-C and C-heteroatom (O, N, Cl, Br, I) bond forming reactions. This article summarizes the developments of Ru, Rh, Pd, and Ir-catalyzed ketone-directed ortho-C-H functionalization reactions in the past two decades. (C) 2014 Elsevier Ltd. All rights reserved.

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