Journal
TETRAHEDRON LETTERS
Volume 55, Issue 18, Pages 2962-2964Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2014.03.096
Keywords
C-H functionalization; Olefination; Oxygen; Palladium; Polyfluoroarenes
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Funding
- National Natural Science Foundation of China (NSFC) [21172242, 20832008]
- SIOC
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The first example of Pd-catalyzed aerobic direct olefination of polyfluoroarenes has been developed. The reaction makes use of molecular O-2 as terminal oxidant, and provides a cost-efficient and environmentally benign access to polyfluoroarene-alkene structures that are of interest in life and material sciences. (C) 2014 Elsevier Ltd. All rights reserved.
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