Journal
TETRAHEDRON LETTERS
Volume 55, Issue 14, Pages 2243-2245Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2014.02.071
Keywords
C-H funtionalization; Transition-metal free; Halogenation; Indoles
Categories
Funding
- National Science Foundation of China [21325206, 21172006]
- National Young Top-notch Talent Support Program
- Ph.D. Programs Foundation of the Ministry of Education of China [20120001110013]
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A novel and efficient transition metal-free C-H bond halogenation of indole derivatives has been developed. 3-Halogenated (3-Br, 3-I) indoles are highly regioselectively produced by this protocol. Simple and readily available halide salts (TBAB, KI) are employed as the halogen source. The transition metal-free and the mild conditions make this protocol very easy to handle and practical. (C) 2014 Elsevier Ltd. All rights reserved.
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