Journal
TETRAHEDRON LETTERS
Volume 55, Issue 12, Pages 1987-1990Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2014.02.009
Keywords
Helical structure; Helicity control; Chiral carboxylate; Zinc complex; Nonlinear effect
Categories
Funding
- Basic Science Research Projects from The Sumitomo Foundation
- Ministry of Education, Culture, Sports, Sciences, and Technology, Japan
- Grants-in-Aid for Scientific Research [25102507, 25109506, 24655114, 25620022, 24108707] Funding Source: KAKEN
Ask authors/readers for more resources
Helicity of single-helical metal complexes, [(LZn3La)-Zn-1](3+) and [(LZn2La)-Zn-2](3+), was dynamically controlled by coordination of chiral carboxylate ions such as mandelate ion. Spectroscopic investigation indicated that two chiral carboxylate ions contribute to the dynamic helicity control. In addition, the coordination of the carboxylate ions resulted in a nonlinear response in the dynamic helicity control. (c) 2014 Elsevier Ltd. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
