Journal
TETRAHEDRON LETTERS
Volume 55, Issue 13, Pages 2130-2133Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2014.02.028
Keywords
Haloenamide; Diene; Hydrohalogenation; Regio- and stereoselective reaction; Enyne
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A simple protocol for regio-, and stereoselective hydrohalogenation of ynamide moieties in 1,3-butadiyne structures is described. The facile approach enables exact syn-addition of HX to the diyne components, giving just single isomer of the corresponding dienes and enynes. (C) 2014 Elsevier Ltd. All rights reserved.
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