Journal
TETRAHEDRON LETTERS
Volume 55, Issue 34, Pages 4681-4689Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2014.06.051
Keywords
Hypervalent iodine; Oxidation; Phenols; Asymmetric catalysis; Catalyst design
Categories
Funding
- University of Minnesota
- NIH [R21DA033556]
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The use of and lambda(3)- and lambda(5)-iodanes in the oxidative dearomatization of phenols is a well-established and general procedure for the construction of cyclohexadienone structures. However, their use in asymmetric dearomatization reactions is quite underdeveloped and, despite work by several research groups over the past several years, a general chiral aryl iodide catalyst has yet to emerge. This Letter will serve to highlight the significant progress that has been made in this area and will reveal some of deficiencies in the literature that the author believes may be hindering further progress. (C) 2014 Elsevier Ltd. All rights reserved.
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