Journal
TETRAHEDRON LETTERS
Volume 55, Issue 30, Pages 4172-4174Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2014.05.068
Keywords
Alcohol; Hydrogen transfer; Rhenium; Homogeneous catalysis; Amination
Categories
Funding
- National Natural Science Foundation of China [21172106, 21372114]
- National Basic Research Program of China [2010CB923303]
- Research Fund for the Doctoral Program of Higher Education of China [20120091110010]
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The rhenium heptahydride complex [ReH7(PCy3)(2)] was found to be an effective homogeneous catalyst for amination of various alcohols through hydrogen transfer mechanism. Under carbon monoxide atmosphere, a variety of primary and secondary alcohols could directly undergo the C-N coupling process. (C) 2014 Published by Elsevier Ltd.
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