4.4 Article

An efficient and reusable vanadium based catalytic system for room temperature oxidation of alcohols to aldehydes and ketones

Journal

TETRAHEDRON LETTERS
Volume 55, Issue 36, Pages 5029-5032

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2014.07.047

Keywords

Vanadyl sulfate; Peroxovanadium complex; tert-Butyl hydroperoxide; Oxidation; Alcohols

Funding

  1. UGC, New Delhi [41 254/2012 (SR)]
  2. UGC
  3. Department of Science and Technology, New Delhi

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A simple and efficient vanadium based catalyst system for the oxidation of primary and secondary alcohols to aldehydes or ketones is reported using tert-butyl hydroperoxide as oxidizing agent and vanadyl sulfate as catalyst at room temperature. The versatility of the catalytic protocol is studied with wide variety of substrates. (C) 2014 Elsevier Ltd. All rights reserved.

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