Journal
TETRAHEDRON LETTERS
Volume 55, Issue 44, Pages 6096-6100Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2014.09.042
Keywords
C-C bond formation; Hydroalkylation; Tetrahydrofuran derivatives
Categories
Funding
- National Natural Science Foundation of China [21302183]
- 'Strategic Priority Research Program' of the Chinese Academy of Sciences [XDA09030102]
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We aimed to describe an efficient CoCl2-catalyzed direct C-C bond formation of tetrahydrofuran (THF) with various alkynes in the presence of tert-butyl hydroperoxide and catalytic amount of acid to obtain vinyl-substituted THFs. Mono- and di-substituted alkynes were suitable for this transformation. (C) 2014 Elsevier Ltd. All rights reserved.
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