Journal
TETRAHEDRON LETTERS
Volume 55, Issue 42, Pages 5739-5741Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2014.08.088
Keywords
C-S coupling; Metal free; Diaryliodonium; Rapid; Chemoselectivity
Categories
Funding
- National Natural Science Foundation of China [21401080, 21371080]
- Natural Science Foundation of Jiangsu Province of China [BK20130125]
- 333 Talent Project of Jiangsu Province [BRA2012165]
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An efficient, general, and highly selective method for the synthesis of aryl sulfides has been developed through metal-free, direct C-S coupling from thioalcohols and diaryliodonium salts. Significantly, the reaction took only 10 min to complete and produced high yields at room temperature. Thus, this methodology proves its value as a versatile synthetic choice for a broad range of aryl sulfides, producing good to excellent yields. (C) 2014 Elsevier Ltd. All rights reserved.
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